Eutectic Point

The eutectic point is when a solid solute, a solid solvent, and a liquid mixture all exist in the same phase. The eutectic point is the lowest temperature at which the liquid phase is stable at a given pressure.

A eutectic system is a homogenous, solid mixture of two or more substances that form a super-lattice that melts or solidifies at a temperature lower than any of the individual ingredients’ melting point. The term is most usually used to describe a mix of metals. Only when there is a precise ratio between the components does a eutectic system form. The word “eutectic” is derived from the Greek words “eu,” which means “good” or “well,” and “tecsis,” which means “melting.”

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Eutectic System and Eutectic Temperature

For all mixing ratios of the component components in a eutectoid, the eutectic temperature is the lowest attainable melting temperature. The super-lattice will release all of its components at this temperature, and the entire eutectic system will melt into a liquid. In contrast, in a non-eutectic mixture, each component will solidify into a lattice at its own specific temperature until the entire material solidifies.

In a eutectic system, one of the components of the lattice melts first when any of the other mixture ratios is heated to the eutectic temperature, but the temperature of the entire system of the mixture must increase for all of the other components of the component lattices to melt. When a non-eutectic mixture cools, each of its components solidifies (during the development of its lattice) at a different temperature until the entire material is solid.

Phase Transition of the Eutectic System

When a substance transitions from one state to another, it is known as a phase transition. At a precise combination of temperature and pressure, every element or substance can transition from one phase to the next.

Eutectic Point

On a phase diagram, the eutectic percentage ratio (on the atomic or molecular ratio axis (X-axis) of the diagram) and the eutectic temperature are the terms used to describe the eutectic point (on the Y-axis of the diagram). The valence electrons of the component species are not always compatible in any of the mixing ratios to form a new type of joint crystal lattice of the combination, hence not all binary alloys have a eutectic point. The melting point and freezing point of the silver-gold eutectic system meet at the pure element endpoints of the atomic ratio axis while significantly separating in the mixed area of the axis.

Examples of Eutectic Systems

In metallurgy and other industries, there are several instances of eutectic systems or eutectoids. Tin-lead (Sn-Pb), which is used for soldering, is one of the most essential eutectics. Another fascinating example is indium-gallium (In-Ga), which is liquid at just above room temperature and allows for simple ohmic connections on semiconductors such as Si. The eutectic point (indicated by E) has a temperature of less than 200°C and a Sn concentration of slightly more than 70%. At the lowest temperature, the eutectic composition melts completely. Without dividing into two parts, the melt will harden immediately. As a result, in order to obtain a sufficiently uniform solid, the eutectic composition does not need to be cooled down exceedingly slowly.

Examples of Eutectic Systems

Uses of Eutectic Alloys

A eutectic system is a combination of chemical compounds or components with a single chemical composition that solidifies at a lower temperature than any other composition containing the same ingredients. The eutectic composition is named after it, and the temperature at which it solidifies is called the eutectic temperature. A eutectic alloy is one that has eutectic behaviour and is made up of two or more components. A eutectic alloy has a certain melting temperature. Eutectic alloys aren’t formed by all binary alloys. Because the valence electrons are incompatible with super-lattice formation, gold-silver does not form a eutectoid.

Both academically and technologically, eutectic alloys are extremely important. These systems have a lower melting point than pure elements and are more fluid, making them ideal for technological applications like casting, welding, and joining. Eutectic alloys are ideal for sealing long narrow joints and high-throughput joining processes like electronic component housings, vacuum brazing of metallized ceramics to metals, or processes that require the minimal presence of harmful volatile impurities due to their free-flowing properties and excellent wettability.